ABSTRACT. In no-till (NT), liming and urea fertilization are performed on the soil surface, which can increase nitrogen (N) losses via ammonia volatilization. On the basis of N fertilization management, gypsum application provides a promising alternative for improving N uptake by plants. Therefore, the objective of this study was to evaluate the N behavior loss by NH3-N volatilization, the soil pH at a depth of 0 - 0.05 m, leaf N content, and N uptake by second-season corn after lime and gypsum application in a Rhodic Ferralsol under NT. Overall, the treatments consisted of a 4 × 4 factorial arrangement with four lime rates (0, 2.6, 5.4, and 8.1 Mg ha-1) and four gypsum rates (0, 4, 8, and 12 Mg ha-1). During the study period, second-season corn was cultivated for two years and fertilized with urea, for which the N losses through ammonia volatilization, soil pH, leaf N content, and N uptake values were quantified. The losses through ammonia volatilization were subjected to nonlinear regression using a logistic model, and the other variables were subjected to linear regressions. The lime applied by broadcasting on the soil surface in the NT increased the pH of the topsoil and increased N losses via NH3-N volatilization in the second-season corn. Further, the N losses in the NT treated with lime accounted for 58% of the applied N, which increased by 2.3 to 2.5% for each Mg ha-1 of lime applied. Therefore, lime or gypsum application did not improve the status of N in second-season corn in soils with low acidity and no S deficiency.

ABSTRACT Novel fertilizer stabilization technologies are needed to decrease ammonia (NH3-N) losses and increase nitrogen use efficiency. Duromide + NBPT is a new technology that combines two molecules, Duromide and NBPT, whose propose is to increase the efficiency of the urease inhibitor NBPT in reducing NH3-N loss from urea. Preliminary results showed that Duromide + NBPT can be a more effective product than just NBPT, particularly under low soil pH and high-temperature conditions. This study aimed to compare the effects of urea + Duromide + NBPT, urea + NBPT, and conventional urea on soil N losses by NH3-N volatilization. The field experiment was conducted on a Latossolo Vermelho Distroférrico (Oxisol) in Campo Mourão, Paraná, Brazil, using a randomized complete block design with treatments arranged in a 2 × 3 factorial, comprising two N doses (45 and 90 kg ha-1) and three N fertilizers (urea + Duromide + NBPT, urea + NBPT, and conventional urea). The NH3-N volatilization data were subjected to nonlinear regression using a logistic model. The NH3-N losses varied according to dose and fertilizer, reaching up to 12.4 % of the applied N in the conventional urea treatment. Urea + Duromide + NBPT was more efficient than urea + NBPT in decreasing NH3-N volatilization. Compared to conventional urea at doses of 45 and 90 kg ha-1 of N, urea + Duromide + NBPT reduced NH3-N volatilization losses by 35 and 54 % and from urea + NBPT by 15 and 33 %, respectively. The new stabilizing technology Duromide + NBPT reduced NH3-N losses by up to 33 % compared to NBPT alone. Ammonia volatilization was influenced by soil moisture. The volatilization peak, observed after 18-19 days of N fertilizer application, was triggered by rainfall events.

ABSTRACT Oxisols ( Latossolos ) are widely distributed in tropical zones and generally characterized by high levels of surface and subsurface acidity. In Brazil, most Oxisols are managed under no-till conditions with surface application of acidity amendments. This study aimed to evaluate lime application strategies (incorporated and surface) for achieving the desired soil base saturation (BS%) levels (44, 60, 70, and 90 %) and the effect of phosphogypsum + lime application on soil chemical properties as well as wheat and corn yield in southern Brazil. Lime incorporation was more effective in reducing the soil acidity and increasing Ca2+ and Mg2+ despite a decrease in organic matter at the soil surface. Phosphogypsum application increased S-SO42- and Ca2+ availability throughout the deeper soil layers and reduced the Mg2+ content in the surface layer. Wheat yield under incorporated lime conditions increased with BS% up to 75, but there was no response to surface application. When phosphogypsum was applied, the wheat yield increased by 8.4 %. For corn, incorporated lime increased the yield up to 445 kg ha-1, which was equivalent to the yield after phosphogypsum application. An increase in the S-SO42- level was the main factor related to the increase in crop yields. In the short term, our results suggest that phosphogypsum applied along with lime is more appropriate than incorporating lime under no-till management conditions.

ABSTRACT Brazil is currently the leading country in no-till (NT) farming, particularly on Ferralsols (Latossolos), the most abundant soil type. These soils are characterized by subsurface acidity that cannot be effectively corrected by surface application of additives. In this situation, the use of phosphogypsum can be advantageous. This study aimed to assess the residual effects of lime and phosphogypsum application on a clayey Ferralsol, and four soybean and two wheat yields in southern Brazil. The area has been cultivated under no-till since 1975. The soil was limed to different base saturation (BS) levels (50, 60, 70, and 90 %) by surface application (SL) or lime incorporation (IL). Three combined treatments were also studied: (i) surface liming to 60 % BS plus standard (3.71 Mg ha-1) phosphogypsum dose (60G1), (ii) surface liming to 70 % BS + standard phosphogypsum dose (70G1); and (iii) surface liming to 70 % BS + double (7.42 Mg ha-1) phosphogypsum dose (70G2). Soil samples were collected 48 months after treatment. Soybean and wheat yield was not influenced by BS levels, however IL increased soybean yield in 2012/13, but reduced soybean and wheat yield in later crops. Phosphogypsum increased wheat yield by up to 12.8 % (2012 season) and 5.2 % (2015 season), but soybean was not influenced. Incorporated liming caused a decrease in soil Al3+ levels until 0.60 m depth, whereas SL decreased Al3+ levels until 0.30 m depth. Surface liming increased Mg2+ levels in the 0.40-0.60 m layer. Incorporated liming reduced soil organic matter in the surface layer. A double dose of phosphogypsum (7.42 Mg ha-1) had a greater residual effect in subsurface layers but caused a decrease in Mg2+ and K+ levels. Therefore, the standard phosphogypsum dose provided the best results. In the very clayey soil in subtropical environment, the effects of SL extend beyond surface layers and are preferable to those of IL, although production was not influenced by BS.

Resumo: Alternativas para evitar perdas e impactos desnecessários no meio ambiente são alcançadas no manejo agrícola. A preparação de sementes com nanofertilizantes antes do plantio reduz as preocupações com a dispersão não-alvo; no entanto, formulações e concentrações devem ser cuidadosamente selecionadas para evitar efeitos indesejados. Aqui, avaliou-se a germinação e o desenvolvimento de plântulas após a iniciação das sementes com CuO NPs, CuO bulk e CuCl2. As sementes foram imersas em soluções primárias de 0, 20, 40, 80 e 160 mg.L-1 para as três fontes de Cu. Após 8 horas de preparação, as sementes foram avaliadas quanto à germinação e vigor (primeira contagem de germinação). Os comprimentos de raiz e parte aérea foram medidos, bem como a biomassa seca de parte aérea e de raízes. A fonte de nanopartículas de cobre não apresenta efeitos tóxicos no crescimento do milho e promove maior biomassa quando comparada às demais fontes. Por outro lado, fontes de CuCl2 mostraram alguns impactos negativos tóxicos nas raízes e parte aérea do milho para todas as doses testadas. Esses achados apoiam o tratamento de sementes com NPs como uma alternativa à entrega de micronutrientes essenciais, como o cobre.

Abstract: Fertilizer formulation alternatives that avoid unnecessary losses and environmental impacts are being investigated in agricultural management. Seed priming with nanofertilizers prior to planting, reduces concerns about non-target dispersion; however, priming formulations and concentrations must be carefully selected to avoid undesired effects. Here, seed germination and seedling development were evaluated after seed priming with CuO nanoparticles (NPs), CuO bulk and CuCl2. The seeds were immersed in priming solutions of 0, 20, 40, 80 and 160 mg.L−1 Cu for the three Cu sources. Following 8 hours priming, the seeds were evaluated for germination and vigor (first germination count). Root and shoot lengths were measured as well as shoot and root dry biomass. The copper NP did not show any toxic effects on corn seed germination and growth, and also promoted higher biomass when compared to the other Cu sources. On the other hand, CuCl2 primed seeds exhibited Cu-toxicity in roots and shoots for all concentrations tested. Bulk Cu priming results indicated the better role of NPs size effects. These findings support NP-seed priming as an alternative to delivery of essential micronutrients, such as copper, to corn seedlings.

ABSTRACT The development of new fertilizer technologies to reduce nitrogen (N) losses from an agricultural system and to increase nitrogen use efficiency (NUE) is a global research objective. Controlled-release nitrogen fertilizers have shown great potential for reducing N losses and synchronizing N release according to crop demand, thereby improving the NUE. The objective of this study was to characterize controlled-release nitrogen fertilizers and compare them with conventional nitrogen sources in terms of N release, N loss via NH3 volatilization, and fertilizer effects on second-season corn. The field experiment was performed on an Ultisol in a randomized block design. The treatments consisted of two conventional nitrogen sources (urea and ammonium sulfate) and three brands of polymer-coated urea (PCU; Agrocote®, FortBlen®, and Kimcoat®). The variables N release and N loss by NH3 volatilization were subjected to nonlinear regression analysis using a logistic model and the Korsmeyer-Peppas model, respectively. Leaf N content and dry matter yield were subjected to the Tukey test, and the morphologies of the PCUs were observed by scanning electron microscopy (SEM). Electron micrographs revealed differences in the number of layers and the thickness of the coatings of the studied PCUs. FortBlen®, containing granules with single- or double-layer coatings with thicknesses ranging from 34.53 to 50.34 µm, promoted more gradual N release and reduced N-NH3 losses by 36.4 % compared with those observed with uncoated urea. Kimcoat® released approximately 98 % of the applied N within 24 hours, resulting in N-NH3 volatilization, and the responses in second-season corn were similar to those with uncoated urea. Although no benefits were observed in second-season corn for PCUs over uncoated nitrogen sources, some PCUs promoted more gradual N release and reduced N-NH3 volatilization, providing a promising alternative for environments prone to N loss.

Baixos teores de matéria orgânica no solo podem limitar o desenvolvimento da soja, devido a baixa disponibilidade de enxofre (S) no solo e pela alta demanda deste nutriente pelas plantas. Uma alternativa para complementar esta necessidade é a aplicação S foliar. O objetivo foi avaliar o efeito da aplicação de fertilizante foliar à base de enxofre na cultura da soja, em diferentes épocas e doses. Os tratamentos foram: (1) 0,0 kg ha-1 de S foliar; (2) 0,5 kg ha-1 de S foliar no estágio de início do florescimento (R1); (3) 0,5 kg ha-1 foliar no estágio de início do enchimento de grãos (R5.1); (4) 0,5 kg ha-1de S foliar nos estádios R1 e R5.1; (5) 1 kg ha-1de S foliar no estádio R1; (6) 1 kg ha-1de S foliar no estádio R5.1; (7) 1 kg ha-1de S foliar nos estádios R1 e R5.1, delineados em blocos ao acaso com 4 repetições. As variáveis respostas foram: massa de mil grãos, produtividade e teores de macro e micronutrientes nos grãos. A produtividade dos grãos aumentou 614 kg ha-1 com aplicação de S foliar em relação à testemunha. A dose que obteve a melhores resultados foi de 0,5 kg ha-1 aplicado nos estádios R3 ou R5.1. A utilização de enxofre elementar via foliar pode ser uma alternativa de complementação.

Low levels of organic matter in soil may limit the soybean crop development due to the low availability of sulfur (S) and the high demand of this nutrient by plants. The foliar fertilization is an alternative to supplement plant request. This study aimed at assessing the effect of applying foliar sulfur fertilizer in the soybean at different time and doses. The treatments studied were: (1) 0.0 kg ha-1 of S foliar; (2) 0.5 kg ha-1 of foliar S in beginning bloom (R1) stage; (3) 0.5 kg ha-1 of foliar at beginning seed (R5.1) stage; (4) 0.5 kg ha-1 of foliar S in R1 and R5.1; (5) 1 kg ha-1 of foliar S in R1; (6) 1 kg ha-1 of S foliar in R5.1; (7) 1 kg ha-1 of foliar S in R1 and R5.1 using randomized block design with 4 replicates. The variables analyzed were: one thousand grain mass, yield and the macro and micronutrient contents in the grains. The soybean yield increased 614 kg ha-1 with the application of foliar sulfur in relation to the control. The dose that obtained the best results was 0.5 kg ha-1 applied into the R3 or R5.1 stage. The use of elemental sulfur via foliar may be an alternative of sulfur supplementation.

ABSTRACT Brazilian soybean producers commonly apply maintenance potassium (K) fertilization during cultivation to restore the K taken up by plants; however, this measure can modify the morphophysiological plant characteristics, since the functions of K are closely related with plant growth and development. This study assessed the morphological changes in soybean plants in response to K rates, sowing fertilization, and the application periods of K fertilization in a Latossolo Vermelho eutroférrico (Oxisol) under a no-tillage system, located in the municipality of Floresta, Paraná. A randomized block design was used in the experiment with four replications in a fully crossed factorial design (5 × 2 × 2). The experiment was carried out in two growing seasons (2015/2016 and 2016/2017), with a total of 80 experimental units. The rates corresponded to the first factor (0, 40, 80, 120, and 160 kg ha-1 of K). The application periods (pre-sowing and post-sowing) were the second factor, and sowing fertilization (0 and 30 kg ha-1 of K) the third. The following variables were measured: shoot dry weight, leaf dry weight, stem dry weight, leaf area, specific leaf area, leaf area ratio, and leaf area index, and these biometric parameters were correlated with soybean yield. The results showed that plants well-supplied with K exploited the environment better and this may be reversed for higher yields since there were correlations between grain yield and the biometric parameters. At lower water availability, the biometric changes were more evident.

ABSTRACT Maghemite (γ-Fe2O3) and hematite (α-Fe2O3) are important iron oxides in Brazilian soils derived from basalt. Maghemite can transform into hematite when exposed to high temperatures. However, isomorphic substitution (e.g., Al3+) may largely influence this process. We analyzed the kinetics of thermal transformation of Al-maghemites into Al-hematites and some of its mineralogical aspects. Synthetic substituted maghemites with different degrees of Al-substitution (0.0, 1.0, 2.0, 2.9, 3.8, 5.6, 6.7, 10.0, 12.0, and 17.1 mol% Al) were subjected to a temperature of 500±10 °C for 0, 5, 10, 16, 64, 128, 192, 360, 720, 2160, 3600, 5040, and 6480 min. After thermal treatment, samples were characterized by X ray diffraction (XRD), differential thermal analysis (DTA), specific surface area (SSA) measurement, and total chemical analysis. XRD patterns were analyzed by Rietveld refinement, and maghemite and hematite contents were calculated using Rietveld refinement and the method proposed by Sidhu. Isomorphic substitution of Fe by Al increased the critical temperature of transformation and the time necessary for maghemite to hematite transformation. Rietveld refinement data showed a better fit than the data adjusted by the Sidhu method. Increasing isomorphic substitution also decreased lattice parameters and mean crystallite dimension (MCD) values in maghemite; but only c-dimension and MCD decreased with increasing Al-substitution in hematite. For maghemite, the SSA increased with isomorphic substitution, rising up to 5.9 mol% Al; for hematite, SSA increased linearly. SSA decreased with heating time, regardless of isomorphic substitution.

ABSTRACT Burning is a common practice in tropical areas and related changes in mineralogy might affect the chemical and physical behavior of soils. Maghemite is a common iron oxide in soils formed from basic rocks in tropical regions. This mineral and hematite are the main pigments in these soils and exhibit high magnetization stemming from the precursor magnetite formed during the weathering process of primary minerals. The objective of the present study was to analyze changes in color, magnetic suceptibility values, Fourier transform infrared spectroscopy (FTIR) spectra, and available Fe and Al contents extracted with 1 mol L-1 KCl during the process of thermal transformation of synthetic Al-maghemites into Al-hematites. Synthetic substituted maghemites with different degrees of Al-substitution (0.0, 1.0, 2.0, 2.9, 3.8, 5.6, 6.7, 10.0, 12.0, and 17.1 mol% Al) were subjected to a temperature of 500 ± 10 °C for 0, 5, 10, 16, 64, 128, 192, 360, 720, 2160, 3600, 5040 and 6480 min. The color of the samples was analyzed by a Munsell system in a colorimeter. Mass-specific magnetic susceptibility (χLF) was measured at low-frequency. Available Fe and Al contents were estimated by a 1 mol L-1 KCl solution. Fourier transform infrared spectroscopy (FTIR) spectra were obtained through use of a Bruker Vertex 70X FTIR spectrophotometer at a spectral resolution of 4 cm-1. Contents of Fe and Al extracted by 1 mol L-1 KCl in Al-hematites were not detected. All samples analyzed exhibited YR hue. Hue proportion decreased with increased heating time, and color changed from brown to red. The increase in isomorphic substitution (IS) led to increased hue values from maghemite to hematite, and the latter then became yellower. The χLF values decreased with an increase in heating time, indicating transformation from a ferrimagnetic phase (maghemite) to an antiferrimagnetic phase (hematite). With increasing IS, the maghemite χLF values decreased. Bands of the initial members (time 0) in the FTIR spectra were indexed as maghemites. The end members after completion of the heat treatment were identified as hematites. The IS of Fe by Al in maghemite influenced the thermal transformation to hematite, as well as the color and χLF of the minerals. The χLF proved to be very efficient in detecting maghemites remaining after thermal processing. Fe and/or Al were not ejected from the hematite crystalline structure after heat treatment.

Maghemitas sintéticas substituídas com Al foram caracterizadas por meio de análise química total, difratometria de raios-X (DRX), espectroscopia Mössbauer (EM) e magnetometria de amostra vibrante (MAV). Objetivou-se com este trabalho determinar as propriedades estruturais, magnéticas e hiperfinas de γ-Fe2-xAl xO3, conforme a variação da concentração de Al.Os resultados de DRX dos produtos sintéticos foram indexados somente para maghemita. Com o aumento da substituição de Fe por Al, o diâmetro médio do cristalito diminuiu e levou todos os picos de difração para maiores ângulos º2θ. A dimensão a0 da cela unitária cúbica decresceu com o aumento de Al, de acordo com a equação a o = 0,8385 - 3,63 x 10-5 Al (R²= 0,94). A maioria dos espectros Mössbauer foi composta de um sexteto, mas na taxa mais alta de substituição de 142,5 mmol mol-1 Al um doubleto e sexteto foram obtidos a 300 K. Todos os parâmetros hiperfinos do subespectro foram consistentes com o alto spin Fe3+ (0,2 a 0,7 mms-1) e sugeriram um forte componente superparamagnético associado com o dubleto. O campo magnético hiperfino dos sextetos decresceram com a substituição de Al [Bhf (T) = 49,751 -0,1202Al; R² = 0,94], enquanto as larguras da linha aumentaram de forma linear. A magnetização de saturação também diminuiu com o aumento da substituição isomórfica.

Synthetic aluminum-substituted maghemites were characterized by total chemical analysis, powder X-ray diffraction (XRD), Mössbauer spectroscopy (ME), and vibrating sample magnetometry (VSM). The aim was to determine the structural, magnetic, and hyperfine properties of γ-Fe2-xAl xO3 as the Al concentration is varied. The XRD results of the synthetic products were indexed exclusively as maghemite. Increasing Al for Fe substitution decreased the mean crystalline dimension and shifted all diffraction peaks to higher º2θ angles. The a0 dimension of the cubic unit cell decreased with increasing Al according to the equation a o = 0.8385 - 3.63 x 10-5 Al (R²= 0.94). Most Mössbauer spectra were composed of one sextet, but at the highest substitution rate of 142.5 mmol mol-1 Al, both a doublet and sextet were obtained at 300 K. All hyperfine parameters from the sub-spectra were consistent with high-spin Fe3+ (0.2 a 0.7 mms-1) and suggested a strong superparamagnetic component associated with the doublet. The magnetic hyperfine field of the sextets decreased with the amount of Al-substitution [Bhf (T) = 49.751 - 0.1202Al; R² = 0.94] while the linewidth increased linearly. The saturation magnetization also decreased with increasing isomorphous substitution.

A toxicidade do alumínio (Al) é um dos fatores mais limitantes para a produtividade. Esta pesquisa foi realizada para avaliar a influência do Al, em solução nutritiva, na altura de plantas, no peso da matéria seca e nas alterações morfoanatômicas de raízes e folhas de milho (Zea mays L.). O experimento foi conduzido em casa de vegetação com tratamentos constituídos de cinco doses de Al (0; 25; 75; 150; e 300 µmol L-1) e seis repetições. As soluções foram constantemente aeradas e o pH foi ajustado a 4,3, inicialmente. A matéria seca da parte aérea e das raízes e a altura das plantas diminuíram significativamente com o aumento da concentração de Al. As raízes de plantas de milho cultivadas em soluções com Al tiveram seu crescimento inibido e apresentaram menos raízes laterais e desenvolvimento do sistema radicular inferior, em comparação com as das plantas-controle. As folhas das plantas crescidas em soluções que continham 75 e 300 µmol L-1 de Al não apresentaram muita diferença anatômica em relação às das plantas-controle. A bainha da folha das plantas exposta ao Al apresentou epiderme uniestratificada revestida por uma fina camada de cutícula e as células da epiderme e do córtex foram as que menos se desenvolveram. No feixe vascular, o metaxilema e protoxilema não tinham paredes secundárias, e o diâmetro de ambos foi muito menor quando comparado com os das plantas-controle.

Aluminum (Al) toxicity is one of the most limiting factors for productivity. This research was carried out to assess the influence of Al nutrient solution on plant height, dry weight and morphoanatomical alterations in corn (Zea mays L.) roots and leaves. The experiment was conducted in a greenhouse with five treatments consisting of Al doses (0, 25, 75, 150, and 300 µmol L-1) and six replications. The solutions were constantly aerated, and the pH was initially adjusted to 4.3. The shoot dry matter, root dry matter and plant height decreased significantly with increasing Al concentrations. Compared to the control plants, it was observed that the root growth of corn plants in Al solutions was inhibited, there were fewer lateral roots and the development of the root system reduced. The leaf anatomy of plants grown in solutions containing 75 and 300 µmol L-1 Al differed in few aspects from the control plants. The leaf sheaths of the plants exposed to Al had a uniseriate epidermis coated with a thin cuticle layer, and the cells of both the epidermis and the cortex were less developed. In the vascular bundle, the metaxylem and protoxylem had no secondary walls, and the diameter of both was much smaller than of the control plants.

A compreensão e a quantificação do impacto dos sistemas de uso e manejo nos teores de C orgânico do solo (COS) e em propriedades físicas são fundamentais para o desenvolvimento de sistemas agrícolas sustentáveis. O objetivo deste trabalho foi avaliar alterações em alguns atributos físicos e COS de um Latossolo Vermelho da região noroeste do Paraná sob diferentes sistemas de uso e manejo: mata nativa, pastagem e as culturas de mandioca e de cana-de-açúcar. Foram coletadas amostras deformadas para determinação da textura, da densidade de partículas, do ensaio de Proctor normal e dos teores de matéria orgânica; e amostras indeformadas, para determinação da densidade do solo (Ds) e porosidade do solo. Os resultados indicaram que os sistemas de manejo estudados induziram alterações nos atributos físicos do solo em relação à mata nativa, o que foi verificado pelos maiores valores de Ds, densidade relativa do solo e densidade máxima do solo e menores valores de macroposidade, porosidade total, COS e estoque de C do solo, na seguinte ordem crescente: pastagem, mandioca e cana-de-açúcar. Contudo, as áreas não são consideradas fisicamente degradadas. Os valores de densidade máxima do solo foram de 1,91, 1,93, 2,00 e 2,03 Mg m-3, e os de estoque de C do solo, de 17,8, 16,6, 12,8 e 12,1 Mg ha-1, para mata nativa, pastagem, mandioca e cana-de-açúcar, respectivamente.

Understanding and quantifying the impact of land use and soil management on soil organic carbon (SOC) levels and physical properties is essential for the development of a sustainable agriculture. The purpose of this study was to evaluate some physical properties and SOC of an Oxisol in the Northwest of the state of Paraná, under different use and soil management systems, i.e., under native forest, pasture, cassava, and sugarcane. Disturbed soil samples were collected for particle size, particle density, proctor and organic carbon analyses and undisturbed samples (rings) to determine bulk density (Ds) and soil porosity. Results indicated that the land use and management systems induced changes in the soil physical properties in comparison to native forest. This was inferred from the higher values of soil Ds, maximum bulk density, and relative bulk density, and the lower values of macroporosity, total porosity, SOC and soil carbon stock, in the following growing order: pasture, cassava and sugarcane. However, the areas are not considered physically degraded.

Foram avaliadas plantas de milho submetidas a diferentes fontes de fertilizantes fosfatados e diferentes concentrações de alumínio em um substrato de areia. O experimento foi conduzido com duas plantas por vaso contendo 2 kg de areia, duas fontes de fósforo (Fosfato Supertriplo -TSP ou Fosfato de Arad -AP) e quatro concentrações de Al. Com o aumento das concentrações de Al houve diminuição dos valores de pH (CaCl2) do substrato. Os valores de cálcio e fósforo aumentaram no substrato nos tratamentos com TSP e AP. As concentrações de cálcio, magnésio, fósforo e de potássio das plantas de milho foram maiores em TSP do que nos tratamentos sem P ou com AP. Como o aumento da concentração de Al observou-se redução na concentração de cálcio, magnésio, fósforo e de potássio nas plantas. A produção de massa seca da parte aérea respondeu positivamente com as fontes de P. Com o aumentou da concentração de Al os valores de massa seca diminuíram significativamente com TSP.

The corn plants were evaluated with different phosphate fertilizer sources and aluminum (Al) concentrations in a sandy substrate. A totally randomized experiment design was set up with two corn plants in the pots containing 2 kg of a sandy substrate, two phosphate sources (Triple Super Phosphate - TSP or Arad Phosphate - AP) and four Al concentrations. When Al concentrations increased, pH (CaCl2) substrate values decreased. There was an increase in the calcium and phosphorus contents in the sandy substrates that received the TSP and AP sources. The calcium, magnesium, phosphorus, and potassium concentrations of the corn plant's shoot were higher in the TSP than without P and AP sources. When the Al concentration increased, the concentration values of the former elements decreased. The dry mass production of the corn plants responded positively to P sources. As the Al concentration increased, the dry mass values decreased significantly in the TSP source.

A maghemita (g-Fe2O3) é um óxido de Fe ferrimagnético comumente encontrado em solos Vermelho-Escuros derivados de rochas basálticas. Os graus variáveis de substituição isomórfica de Fe3+ por diferentes metais (por exemplo, Ti4+, Al3+, Mg2+, Zn2+ e Mn2+) e não-metais, na estrutura da maghemita, influenciam algumas características cristaloquímicas deste óxido de Fe. Maghemitas sintéticas substituídas com Zn foram preparadas por meio de co-precipitação em meio aquoso alcalino contendo FeSO4.7H2O e quantidades crescentes de ZnSO4.7H2O, para dar origem a uma contínua sucessão de substituição de Fe3+ por Zn2+, nas seguintes proporções: 0,0, 0,025, 0,05, 0,10, 0,15, 0,20 e 0,30 mol mol-1. O objetivo deste trabalho foi avaliar as alterações cristaloquímicas de maghemitas sintéticas substituídas com Zn. Após a síntese, o precipitado preto formado foi aquecido a 250 °C durante 4 h, formando uma maghemita de cor marrom, que foi caracterizada por análise química, difração de raios X (DRX), área superficial específica e suscetibilidade magnética. Os níveis de substituição isomórfica observados foram de 0,0013, 0,0297, 0,0590, 0,1145, 0,1764, 0.2292 e 0,3404 mol mol-1, formando uma série de maghemitas de Fe2Zn0O3 até Fe1,49Zn0,770O3. O incremento da substituição de Fe3+ por Zn2+ [Zn mol mol-1] aumentou a dimensão a0 da cela unitária cúbica da maghemita, de acordo com a equação de regressão: a0 = 0,8343 + 0,02591Zn (R² = 0,98). Por outro lado, o diâmetro médio do cristalito e a suscetibilidade magnética das maghemitas estudadas diminuíram com o aumento da substituição isomórfica.

Maghemite (g-Fe2O3) is the most usually found ferrimagnetic oxide in red basalt-derived soils. The variable degrees of ionic substitution of Fe3+ for different metals (e.g. Ti4+, Al3+, Mg2+, Zn2+, and Mn2+) and non-metals in the maghemite structure influence some cristallochemical features of this iron oxide. In this study, synthetic Zn-substituted maghemites were prepared by co-precipitation in alkaline aqueous media of FeSO4.7H2O with increasing amounts of ZnSO4.7H2O to obtain the following sequence of Fe3+ for Zn2+ substitutions: 0.0, 0.025, 0.05, 0.10, 0.15, 0.20, and 0.30 mol mol-1. The objective of this work was to evaluate the cristallochemical alterations of synthetic Zn-substituted maghemites. The dark black synthetic precipitated material was heated to 250 °C during 4 h forming a brownish maghemite that was characterized by chemical analysis as well as X ray diffraction (XRD), specific surface area and mass-specific magnetic susceptibility. The isomorphic substitution levels observed were of 0.0013, 0.0297, 0.0590, 0.1145, 0.1764, 0.2292 and 0.3404 mol mol-1, with the formation of a series of maghemites from Fe2Zn0O3 to Fe(1.49)Zn(0.770)O3 . The increase in Fe3+ for Zn2+ substitution, [Zn mol mol-1] increased the dimension a0 of the cubic unit cells of the studied maghemites according to the regression equation: a0 = 0.8343 + 0.02591Zn (R² = 0.98). On the other hand, the mean crystallite dimension and mass-specific magnetic susceptibility of the studied maghemites decreased with increasing isomorphic substitution.